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Lye is a caustic base, either sodium hydroxide (soda lye) or potassium hydroxide (potash lye). It's most commonly used for making [[soap]] by mixing lye with animal fat, but can also be used to cure and tenderize foods in small amounts.
Lye is the common name of a caustic hydroxide base, either sodium hydroxide (soda lye) or potassium hydroxide (potash lye). It's most commonly used for making [[soap]] by mixing lye with fats, but can also be used to cure and tenderize foods in small amounts. Sodium hydroxide may additionally be used in the production of paper, and water treatment.
== Production ==
Potash lye is generally easier to produce using primitive methods than soda lye, as [[potash]] (K<sub>2</sub>CO<sub>3</sub>) is much easier to procure than [[Soda Ash|soda ash]] (Na<sub>2</sub>CO<sub>3</sub>), the latter of which requires the use of the ash from certain coastal plants, whereas former merely needs wood ash. 


The general procedure is as follows, first prepare a solution of slaked lime by adding quicklime to water, 2 parts by weight of quicklime for potash, 1 part by weight for soda ash.  Do this slowly as the reaction is very exothermic.  Next, simply add your carbonate of choice into the solution, either 5 parts by weight of potash or 2 parts by weight of soda lime.  Then the solution can be carefully boiled down in a non-metallic container (a solution of hot lye will easily eat through most metals, and will easily eat through flesh), leaving relatively pure lye.  This can be recrystallized if higher purity is needed.


Sodium hydroxide can additionally be used in the production of paper, and water treatment.
Two reactions have occurred in this process.  First, the slaking of quicklime to produce slaked lime:


CaO + H<sub>2</sub>O → Ca(OH)<sub>2</sub>


Potassium hydroxide can additionally be used in the production of [[saltpeter]].
Then, the double displacement of the carbonate with the slaked lime to produce lye and limestone:


== Materials needed ==
K<sub>2</sub>CO<sub>3</sub> + Ca(OH)<sub>2</sub> → 2 KOH + CaCO<sub>3</sub>


* A salt-tolerant '''plant''' as glassworts, saltworts, or kelp
or,
* '''[[Fire]]'''
* '''[[Water]]'''
* [[Quicklime|'''Limewater''']]


== Crafting instructions ==
Na<sub>2</sub>CO<sub>3</sub> + Ca(OH)<sub>2</sub> → 2 NaOH + CaCO<sub>3</sub>
Soda lye is much easier to produce compared to potash lye, but which you can make is dependent on your location.
 
 
'''Soda Ash Lye'''
 
First, burn any 'halophyte' (salt tolerant) plant such as glassworts, saltworts, or kelp, leach the ashes, and boil the resulting liquid to produce [[Soda Ash|soda ash]] (sodium carbonate). Add the resulting soda ash to [[Quicklime|limewater]] for a final product of lye (sodium hydroxide).
 
 
'''Wood Ash Lye'''
 
Start by burning wood, and leaching the ash. Boil off the resulting water to create potash. When mixed with [[Quicklime|limewater]], it produces lye (potassium hydroxide). While easier to create, this method is much less favorable to the soda ash method, as the resulting lye is of lower quality and yeild.


== Uses ==
== Uses ==
Lye is a powerful base, particularly useful in the production of [[Soap|soap.]]
Lye is a powerful base, particularly useful in the production of [[soap]]. Soda lye in particular may also be used in the production of [[paper]] from wood, via soda pulping.


== Dependencies ==
== Dependencies ==

Revision as of 10:11, 8 May 2025

Lye is the common name of a caustic hydroxide base, either sodium hydroxide (soda lye) or potassium hydroxide (potash lye). It's most commonly used for making soap by mixing lye with fats, but can also be used to cure and tenderize foods in small amounts. Sodium hydroxide may additionally be used in the production of paper, and water treatment.

Production

Potash lye is generally easier to produce using primitive methods than soda lye, as potash (K2CO3) is much easier to procure than soda ash (Na2CO3), the latter of which requires the use of the ash from certain coastal plants, whereas former merely needs wood ash.

The general procedure is as follows, first prepare a solution of slaked lime by adding quicklime to water, 2 parts by weight of quicklime for potash, 1 part by weight for soda ash. Do this slowly as the reaction is very exothermic. Next, simply add your carbonate of choice into the solution, either 5 parts by weight of potash or 2 parts by weight of soda lime. Then the solution can be carefully boiled down in a non-metallic container (a solution of hot lye will easily eat through most metals, and will easily eat through flesh), leaving relatively pure lye. This can be recrystallized if higher purity is needed.

Two reactions have occurred in this process. First, the slaking of quicklime to produce slaked lime:

CaO + H2O → Ca(OH)2

Then, the double displacement of the carbonate with the slaked lime to produce lye and limestone:

K2CO3 + Ca(OH)2 → 2 KOH + CaCO3

or,

Na2CO3 + Ca(OH)2 → 2 NaOH + CaCO3

Uses

Lye is a powerful base, particularly useful in the production of soap. Soda lye in particular may also be used in the production of paper from wood, via soda pulping.

Dependencies

See also